CHEMISTRY – II(G108)


CHEMISTRY  II(G108)
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Credit: 3
Curri. Ref. No.: G108
Prerequisite: G107
Total marks: 150
Total Contact hrs :60
Lecture: 30Tutorial:0 Practical:30
Theory: 100= End Term Exam: 70 +P.A: 30
Practical: 50= End Term Exam: 25+   P.A : 25
THEORY   Total Periods                 :                                                                                              
UNIT
TOPIC/SUB-TOPIC
HRS

1
ELECTROCHEMISTRY :Define conductor, insulator, semi-conductor, electrolyte and non-electrolyte with examples. State postulates of Arrhenius’s and electrolytic theory of dissociation. Demonstrate the phenomenon of electrolysis. State and explain Faraday’s 1st and 2nd laws of electrolysis. Define and explain conductance, specific conductance, molar conductance, electrochemical cell. Solve problems on electrolysis. Solve problems, Assignment and Class test.
4
2
FUEL: Explain importance of fuels in industries. Define ‘fuel’ and ‘combustion of fuel’ with examples. State the classification of  fuels into two different ways, namely Classification based upon occurrence with examples. Classification based upon state of aggregation with examples. Define calorific value and mention its units. Distinguish between gross (or higher) and net (or lower) calorific value. State the relative merits and demerits of solid, liquid and gaseous fuel. State the availability of different fuels in India. Define coal. State and explain origin of coal. Classify coal by rank. Define pulverized coal. State the advantage and disadvantage of pulverized coal. Explain proximate and ultimate analysis of coal. Define ‘Petroleum’ or ‘Crude oil’. Describe the fractional distillation of crude petroleum. Name the main products obtained from crude petroleum and mention their respective boiling ranges and uses. State  and  explain  important  properties of   liquid fuels namely,  viscosity,  flash  and  fire point, smoke  point, aniline  point, knocking,  octane number, cetane number, anti-knocking properties. State composition, preparation and industrial application of coal gas, water gas, producer gas, LPG, natural gas and gobar gas. Solve problems, Assignments and class tests.
10
3
LUBRICANTS :Define ‘lubricant’ and ‘lubrication’. Mention the major functions of a lubricant. Different types of lubricants with examples Applications. Solve problems, Assignments and class tests
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4
CORROSION :Define corrosion. Describe the causes of corrosion. State the different types of corrosion of metal. Explain chemical corrosion of metals and mention the names of the corrosion products. Explain rusting of iron. Name the various methods of corrosion control. Solve problems, Assignments and class tests
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PROTECTIVE COATING   : State the necessity of protective coating. State the main types of protective coatings.Recall the different kinds of organic and inorganic (or metallic) protective coating. Explain the term “Paint ” State the functions of component-drying oil, pigment, driers and thinners with examples. Varnish, types and application. Solve problems, Assignments and class tests
2
6
ORGANIC CHEMISTRY: Organic chemistry and its scope in various industries. Tetravelancy of Carbon atom Functional groups. Distinguish between organic and inorganic compounds. Homologous series-alkane, alkene, alkyne, alcohol, aldehyde, ketone, ether, carboxylic acid.(general formula). Preparation method of Methane, ethane and ethylene. Benzene and its preparation and discuss its derivatives.
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POLYMER AND PLASTICS :Define  polymer. The types of polymerization. Classify polymers Properties of thermoplastics and thermosetting polymers. Define plastics. Name important plastic materials with their properties and uses (in tabular form). Namely :  Polythene, Polypropylene, polystyrene, PVC, Nylon, Terelene,Neoprene,  Bakelite, Urea-formaldehyde and PET. Mention examples of plastics used in different situations :  Electrical insulation. Lubrication. Ropes and beams. Optical lens. Adhesives. Pipes and housing.  Fibre glass.  Carry bag. Solve problems, Assignments and class tests
4

PRACTICAL:Suggested list of experiments:
1.       To determine calorific value of solid fuel using Bomb Colorimeter.
2.       To find the proximate analysis  (% moisture, %Ash, %volatile matter) of a given sample of coal
3.       To determine the viscosity of petroleum oil by using Red-wood Viscometer
4.       To determine smoke point of petroleum(Kerosene)  products by using Smoke meter
5.       To determine flash point of  petroleum products (Petrol)by using  Pensky-Martein instrument
6.       To determine the aniline point of petroleum products by using Aniline point Instrument
7.       To determine the conductivity & TDS of water by Conductivity meter.

SUGGESTED LEARNING RESOURCES:
Text Books:
1.   Modern Intermediate Chemistry Part I and Part II
2.   By R.N. Nanda, A.K. Das , Y.R Sharma
3.   Engineering Chemistry by Jain & Jain
4.   A Text Book of Polytechnic Chemistry by J.P. Mehta & Jain and Jain
5.   Industrial Chemistry by B.K. Sarma
Reference Books
1.   Intermediate Chemistry by R.K. Samal
Suggested List of Equipment :                                  
Pensky- Martein instrument. Red-wood Viscometer
Smoke meter. Bomb Calorimeter. Conductivity-TDS meter
Aniline point meter. Muffle Furnace. Hot air oven. Electronics balance. Different sieve trays.  Glassware, Porcelin ware, and reagent